Metal-free Catalyst B2S Sheet for Effective CO2 Electrochemical Reduction to CH3OH

Considering the problems of high costs, low catalytic activity and selectivity in the metal-based catalysts for CO₂ electroreduction, we apply boron-containing metal-free B₂S sheet as an alternative to the traditional metal-based catalysts. Reaction energy calculations identify the preferred “Formate” pathway for CO₂ conversion to CH₃OH on B₂S, in which the thermodynamic energy barrier obtained by using the Computational Hydrogen Electrode model is 0.57 eV, and the kinetic energy barrier obtained by searching the transition states is 1.18 eV. Another possible reaction pathway, “RWGS+CO-hydro”, is suppressed and the hydrogen evolution reaction (HER) side reaction is nonspontaneous. Compared to Cu(211) with the highest catalytic activity among all transition metals, B₂S sheet exhibits a better catalytic activity with a lower overpotential for CO₂ reduction and a better selectivity that suppresses the non-target reaction.     

Wiggler聚焦带状注速调管束管的研制

 对Wiggler聚焦带状注速调管电子注截面、聚焦磁场和直流通过率进行了测试,分析了Wiggler聚焦的特点,获得了提高Wiggler聚焦带状注束管直流通过率的调试方法。测试结果表明：同一组磁钢摆放方式不同,电子注的通过率会相差很大;聚焦磁场和电子注匹配不好时,会出现通过率为零的情况。不同周期的直流测试结果表明9 mm周期最佳,在磁场均匀性较差、电压较低的情况下都能获得良好的直流通过率。     

四苯硼钠-季铵盐容量法快速测定造纸法再造烟叶中的钾含量

采用四苯硼钠-季铵盐容量法对造纸法再造烟叶中的钾含量进行了检测.通过精密度试验和加标回收试验对方法的重复性和回收率进行了考察,结果表明:该检测方法具有较好的重复性,相对标准偏差为1.7%(n=6),回收率达到99.14%.该法和流动分析仪(AA3)的检测结果对比表明两种方法的检测结果具有较好的一致性.该研究对造纸法再造...     

均质多边形薄板绕任一对角线转动的转动惯量

运用均质三角形薄板对任一边、对过顶点且与对边平行的轴的转动惯量公式,得到了用薄板的质量、边长及对角线长表示的均质多边形薄板对任一对角线的转动惯量.     

Wiggler磁场聚焦带状电子注

 带状电子注在螺线管磁场作用下传输时,易形成Diocotron不稳定性,导致电子注崩溃。采用Wiggler磁场聚焦带状电子注能防止Diocotron不稳定性。研究了Wiggler磁场聚焦带状注的作用机理,得出带状电子注在Wiggler场作用下的包络方程。结合理论分析,使用3维粒子模拟程序对带状电子注的Diocotron不稳定性和Wiggler磁场抑制不稳定性分别进行了模拟。研究表明:合适的选择磁场大小和周期能有效抑制Diocotron不稳定性,使得设计带状电子注行波管成为可能。     

First-Principles Study on Electronic and Optical Properties of Graphene-Like Boron Phosphide Sheets

Two-dimensional semiconducting materials with moderate band gap and high carrier mobil-ity have a wide range of applications for electronics and optoelectronics in nanoscale. On the basis of first-principles calculations, we perform a comprehensive study on the electronics and optical properties of graphene-like boron phosphide (BP) sheets. The global structure search and first-principles based molecular dynamic simulation indicate that two-dimensional BP sheet has a graphene-like global minimum structure with high stability. BP monolayer is semiconductor with a direct band gap of 1.37 eV, which reduces with the number of layers. Moreover, the band gaps of BP sheets are insensitive to the applied uniaxial strain.= The calculated mobility of electrons in BP monolayer is as high as 10⁶ cm²/(V·s). Lastly, the MoS₂/BP van der Waals heterobilayers are investigated for photovoltaic applications, and their power conversion efficiencies are estimated to be in the range of 17.7%－19.7%. This study implies the potential applications of graphene-like BP sheets for electronic and optoelectronic devices in nanoscale.     

冲击作用下含预制裂纹梁柱试件的动态断裂

利用焦散线实验系统,进行了冲击加载下含预制裂纹梁柱试件的断裂实验,研究了梁柱试件的梁柱节点、梁上和柱端裂纹的扩展轨迹、扩展速度和应力强度因子的变化规律。实验结果表明:受冲击后,试件首先在梁柱节点处开裂,并在裂纹扩展过程中发生明显的曲裂运动,证明梁柱节点处最容易受到破坏。预制裂纹条数越多,梁柱节点处开裂越晚,说明裂纹条数少,能量可以在裂纹尖端积聚得更集中、更快。含柱端预制裂纹的试件,2条裂纹的开裂相隔时间要长于含梁上预制裂纹的试件;同时,试件的第2条裂纹优先在梁上裂纹处开裂,说明固端支座比简支梁断裂需要更多的能量。随着预制裂纹的增多,梁上裂纹在扩展过程中的曲裂现象减弱, 由于部分能量在柱端裂纹处积聚,用于推动梁上裂纹扩展的能量相应地减少。并且由于柱端裂纹的存在,梁上裂纹受到的拉应力分量减小,导致裂纹尖端受到弯矩变小,影响了裂纹的曲裂运动。     

Cattaneo-Christov heat flux model for third-grade fluid flow towards exponentially stretching sheet

The Cattaneo-Christov heat flux in the two-dimensional (2D) flow of a third-grade fluid towards an exponentially stretching sheet is investigated. The energy equation is considered through thermal relaxation. Similarity transformations are accounted to obtain the ordinary differential systems. The converted non-dimensional equations are solved for the series solutions. The convergence analysis of the computed solutions is reported. The graphical results of the velocity and temperature profiles are plotted and elaborated in detail. The results show that the thermal relaxation enhances the temperature gradient while reduces the temperature profile.     

CTOD试验焊缝表面开缺口试样裂纹前沿平直度研究

对于裂纹尖端张开位移(CTOD)试验,焊缝试样中预制疲劳裂纹前沿平直度直接影响了试样制备的合格率,是试验的关键难题之一．试验中常对试样进行预处理以提高裂纹前沿平直度,但由此也使试验结果与实际情况产生一定差异．本文深入研究规范BS7448: Part2中对焊缝试样取样方向的规定,对表面开缺口试样裂纹尖端焊接残余应力进行分析,运用大型有限元软件ANSYS模拟90mm厚钢板焊接过程,求解了横向残余应力沿板厚方向及焊缝方向的分布规律,研究出横向残余应力分布是影响焊缝试样预制裂纹前沿平直度的主要原因,并通过试验进行验证．试验结果表明,表面开缺口试样可不经过局部韧带压缩等预处理而得到合格的裂纹前沿平直度,试验不改变原焊缝残余应力,可测得更加接近焊缝实际情况的CTOD韧度值,给CTOD试验中合理选取焊缝试样取样方向提供了新思路．     

Heat transfer characteristics of thin power-law liquid films over horizontal stretching sheet with internal heating and variable thermal coefficient

The effect of internal heating source on the film momentum and thermal transport characteristic of thin finite power-law liquids over an accelerating unsteady horizontal stretched interface is studied. Unlike most classical works in this field, a general surface temperature distribution of the liquid film and the generalized Fourier’s law for varying thermal conductivity are taken into consideration. Appropriate similarity transformations are used to convert the strongly nonlinear governing partial differential equations (PDEs) into a boundary value problem with a group of two-point ordinary differential equations (ODEs). The correspondence between the liquid film thickness and the unsteadiness parameter is derived with the BVP4C program in MATLAB. Numerical solutions to the self-similarity ODEs are obtained using the shooting technique combined with a Runge-Kutta iteration program and Newton’s scheme. The effects of the involved physical parameters on the fluid’s horizontal velocity and temperature distribution are presented and discussed.